Are these polyester or rayon?

Polyester which is stronger than rayon.

how many yards or meters come on each spool?

1,000 meters or 1,094 yards on each spool of Isacord 40

How big are the cones of thread? Will they work well on a commercial embroidery machine? I've used Madeira in the past.

They are mini spools/cones. Work well with smaller machines. You might prefer king cones.

Does this embroidery thread numbers match up with the color mumbers on my embroidery cards?

Probably not. My embroidery machine has a place in settings to change what kind of embroidery thread you are using. This is excellent thread.

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Product Care Instructions	Machine Wash
Material Type	Thread
Item Length	39370.08 Inches
Item Weight	2.9 Pounds
Color	Assorted

Isacord Quality Embroidery thread set

Details

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Specifications

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